Sovereignty Module: Mix the Melt

Cover of Mix the Melt
Mix the Melt
Complete Glaze Chemistry: From Raw Materials to Formulated Glazes
⟁ cover painted for this edition — the source module carried no illustrations

Complete Glaze Chemistry: From Raw Materials to Formulated Glazes

Glaze chemistry empowers the potter to create, modify, and troubleshoot glazes from raw materials. This campaign covers glaze structure, unity formula, material substitution, and testing methodology.

Chapter 1: Glaze Structure

ComponentRoleExamples
Glass formerCreates the glass matrixSilica (SiO2)
FluxLowers melting temperatureFeldspar, whiting, talc
StabilizerPrevents glass from runningAlumina (Al2O3) from kaolin
ColorantAdds colorIron, copper, cobalt oxides
OpacifierMakes glaze opaqueTin oxide, zirconium
Surface modifierChanges textureCalcium, barium, lithium

Chapter 2: Unity Molecular Formula (UMF)

The UMF expresses a glaze as molecular ratios: 1) Fluxes (RO/R2O) are set to total 1.0. 2) Alumina (Al2O3) is expressed as a ratio to fluxes. 3) Silica (SiO2) is expressed as a ratio to fluxes. 4) This allows comparison between any two glazes regardless of recipe format.

ConeAl2O3 RangeSiO2 RangeCharacter
06 (low fire)0.10-0.251.5-2.5Bright colors, soft surface
6 (mid fire)0.25-0.452.5-4.0Balanced, durable
10 (high fire)0.35-0.553.5-5.5Hard, durable, subtle color

Chapter 3: Common Glaze Materials

MaterialProvidesTemperatureNotes
Feldspar (potash)K2O, Al2O3, SiO2AllPrimary high-fire flux
Feldspar (soda)Na2O, Al2O3, SiO2AllSlightly lower melting
WhitingCaOMid-highPrimary calcium source
Kaolin (EPK)Al2O3, SiO2AllKeeps glaze in suspension
Silica (flint)SiO2AllGlass former
TalcMgO, SiO2Low-midFlux and silica source
DolomiteCaO, MgOMid-highCalcium and magnesium
WollastoniteCaO, SiO2Mid-highCalcium without CO2
Bone ashCaO, P2O5Mid-highOpalescence

Chapter 4: Colorants

OxidePercentageOxidation ColorReduction Color
Iron oxide (Fe2O3)1-10%Amber, brown, redGreen, celadon, tenmoku
Copper oxide (CuO)0.5-3%Green, turquoiseRed (copper red)
Cobalt oxide (CoO)0.25-2%BlueBlue
Manganese dioxide1-5%Purple-brownBrown
Chrome oxide (Cr2O3)0.5-2%GreenGreen
Rutile (TiO2)2-8%Tan, cream, variegatedSimilar
Nickel oxide (NiO)0.5-3%Gray, brown, greenSimilar

Chapter 5: Testing Methodology

Test TypeMethodInformation Gained
Line blendVary one material in stepsEffect of single variable
Triaxial blendVary three materialsInteraction of three variables
Volumetric blendMix measured volumesQuick screening
Tile testApply to test tile, fireSurface quality, color
Cup testApply to functional formDurability, food safety
Limit studyPush one variable to extremesFind boundaries

Reference Card

  1. Silica is the glass (every glaze is fundamentally melted silica; all other materials serve to modify the melting temperature, surface quality, and color of this glass). 2. Alumina prevents running (without alumina, glaze flows off vertical surfaces; alumina stiffens the melt, keeping the glaze where it is applied; kaolin is the primary alumina source). 3. Fluxes lower the melting point (pure silica melts at 3100°F; fluxes lower this to practical kiln temperatures; different fluxes produce different surface qualities). 4. The UMF enables comparison (a recipe in grams tells you nothing about glaze chemistry; the UMF reveals the molecular relationships that determine how a glaze behaves). 5. Test systematically (changing multiple variables simultaneously makes it impossible to know which change caused the result; change one variable at a time in controlled tests). 6. Keep detailed records (every test tile must be labeled with the recipe, clay body, firing temperature, and atmosphere; without records, successful results cannot be reproduced). 7. Glaze chemistry is the potter's deepest knowledge (understanding why a glaze behaves as it does, rather than just following recipes, gives the potter the power to create new glazes and solve problems). 8. The interaction of fire and chemistry creates beauty (the colors and surfaces of pottery glazes emerge from chemical reactions at extreme temperatures; this alchemy of earth and fire is the heart of the ceramic arts).
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